Isn't the whole problem with alexa, in this case, that the cross-section alexa trackees, is not necessarily the cross-section of people who would be interested in octopart?
For example, a very big site, you have enough trackees to make a reasonably statistically valid sample. But smaller sites, you don't see as many trackees, so you set the error bars higher.
Sure, I agree that the system is flawed anyway, seeing as how I don't know a single person who installs the alexa toolbar, and amongst techie sites it's usage is probably 0.
Huge error bars on a near zero estimate don't mean a whole lot except that the experiment producing the data is flawed.
I don't think alexa "scales up." If they do, then, you're right, there is uncertainty. If they don't, I don't think there's a concept of an error bar here. They track how many people go to what sites. Aside from a few dropped packets here or there, there is no uncertainty in that measurement. Therefor, there is no way to measure that sort of error bar. (Right?)