Regulation, societal norms drafted from the start to ensure transparency, and the "greater good" spirit that, one could easily argue, would be prevalent in those who would choose to risk their lives to leave this rock behind... all those things would form the framework by which our offspring would ensure that they're capable of learning from the mistakes of their forebears.
I believe that, as a race, we're too late to undo the damage we've done to our environment. The patient (our way of life) is terminal, we can only hope to make ourselves comfortable in our waning years without unnecessarily spreading the disease.
But, as cliché as it sounds, I am not hopeless, and I simply cannot allow myself to believe that future generations would do the same thing if they had another planet - or even this one - to start over again. I MUST believe that part of the human condition includes learning from and not repeating the mistakes that cost billions of lives.
I see the whole problem as related to manifest destiny, either economic or religious. Pure free markets will save us, and/or so will some deity. Because such faith can't possibly be wrong, can't possibly lead us astray to the degree the species ends.
Is that so?
As for what stops someone buying a seat on that one-way ride to a brave new world? Two things:
1) Your hypothetical buyer isn't actually that brave.
2) The same reason people can't rush the cockpit of a fully loaded airliner any longer. The rest of the passengers know it's in their best interests, as a group, to prevent that from happening.