BTW, I accidentally downvoted you, did not mean to! Sorry for the loss of an internet point. It wasn't mean to discourage your comment.
But I think that as electricity gets cheaper and cheaper, and as fossil fuels have a pigovian tax levied on them, that eventually synthetic or biofuels will be more cost effective than fossil fuels. Electricity is going to get super cheap, and there's going to be times when supply outpaces demand. If the electricity would go to waste otherwise, something that's 40% efficient may be a good use of it.
Coal. Using it like this you avoid all the pollution problems (all the impurities are captured inside the process and not simply emitted).
True you still emit some extra CO2, but that vast majority of the energy content of gasoline does not come from the coal, it's added from the solar power.
So even though you do still emit CO2, as a percentage it's much more minimal.