To elaborate, even if you do call CLUSTER[1] to enforce a physical ordering, the primary key is not the default (there is no default).
1. http://www.postgresql.org/docs/9.5/static/sql-cluster.html
1. http://www.postgresql.org/docs/9.5/static/sql-cluster.html
Primary Key is implemented as a unique index coupled with a not null constraint. It's essentially syntactic sugar.