Some limited info for other fields.
For the engineering PhD programs (chemical, biomedical, electrical, and mechanical) I'm familiar with at (what was once termed) Carnegie R1 universities, the split ends up being around 50/50 for academia vs industry track after graduation. For bio at the same schools, I saw the same as you, near unity for academia. Of my engineering PhD cohort, I was the only 1 of 14 who founded a startup.
I think research md is the field to be in. Md/phd. Plenty of jobs always in demand.
I don't think you can really encourage someone to go for a MD/PhD in good conscience now. It takes too long now and is of questionable benefit. I've interacted with many smart MD/PhDs who were pushing 40 and were still not attendings / lacked their own lab. Your career prospects are severely constrained at that point.
I don't know a single person in my program who actually said they wanted to work in industry (other than the company founders).
Perhaps it's different in other fields.