Nelyah
I never learnt anything about advanced algorithmic, or graph theory before, or language semantics. But in the end, by knowing all that I really look at a problem with a different point of view than before. I am able to imagine some new tricky algorithm etc.
All of that to say : It depends on what you seek going to college. You will be bored if it's just learning some new language, because you either know them already, or you will go faster than the course. But if you want to learn some more theoretical knowledge, you will learn some new stuff for sure. Then again, I don't know where you live, and college might be quite expensive in some country, so I can't tell if it's really worth the money (since you already have some years as a developper). But it is totally worth the time imo.